Synthesis of trifluoromethylsulfur
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Synthesis of trifluoromethylsulfur

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Published .
Written in English


Book details:

Edition Notes

StatementE.A. Tyczkowski.
SeriesPB 233 149
ID Numbers
Open LibraryOL18445768M

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(). Synthesis of Trifluoromethyl Selenides. Phosphorus, Sulfur, and Silicon and the Related Elements: Vol. , No. 1, pp. Cited by: Synthesis of trifluoromethyl arenes. Related: Recent Literature. A copper-catalyzed trifluoromethylation of aryl- and alkenylboronic acids with Togni’s reagent proceeded in good to excellent yields for a range of different substrates including heteroarylboronic acids and substrates with a variety of functional groups under mild reaction. The prediction of environmental fate for trifluoromethyl sulfur pentafluoride (SF5CF3), a potent greenhouse gas. Journal of Hazardous Materials , (3), Cited by: 9. Y. Zhao, J. Zhu, C. Ni, J. Hu, Synthesis, , Related N -Heterocyclic Carbene Catalyzed Highly Chemoselective Intermolecular Crossed Acyloin Condensation of Aromatic Aldehydes with Trifluoroacetaldehyde Ethyl Hemiacetal.

  Journal of Fluorine Chemistry, 66 () Synthesis of trifluoromethyl aryl derivatives via difluorocarbene precursors and nitro-substituted aryl chlorides Jian-Xing Duan, De-Bao Su, Jian-Ping Wu and Qing-Yun Chen* Shanghai Institute of Organic Chemistry, Academia Sinica, Lingling Lu, Shanghai (China) Abstract Treatment of aryl chlorides containing electron .   The asymmetric synthesis of (-)-quinocarcin via a 1,3-dipolar cycloadditive strategy. Journal of the American Chemical Society. Paramagnetic dioxygen complex of iron(II) derived from a picket fence porphyrin. Further models for hemoproteins. Journal of the American Chemical Society.   Typical procedure for the synthesis of 1,4-diaryl(trifluoromethyl)benzene (8a–m) The reaction was carried out in a pressure tube. To a dioxane suspension (5 mL) of the 1,4-dibromo(trifluoromethyl)benzene (6), Pd(PPh 3) 4 (3–5 mol%) and of the arylboronic acid (2) was added an aqueous solution of K 2 CO 3 (2 M, 1–2 mL). The. This article is cited by 25 publications. Ming-Ju Huang and John D. Watts. Theoretical Characterization of the F2O3 Molecule by Coupled-Cluster Methods.

  Journal of Fluorine Chemistry, 3 (/74) Elsevier Sequoia S.A., Lausanne - Printed in Switzerland FLUORINATION OF PERFLUOROALKYLSULFENYL CHLORIDES, PERFLUORODIALKYL DISULFIDES AND PERFLUORODIALKYL SULFIDES WITH CHLORINE MONOFLUORIDE TAKASHI ABE* AND JEAN'NE M. SHREEVE** Department of Chemistry, . Reagents Trifluoromethyltrimethylsilane. Preparation of the trifluoromethyltrimethylsilane was reported by Ingo Ruppert in In , Prakash and Olah first reported activation of TMSCF 3 by fluoride to perform nucleophilic trifluoromethylation of carbonyl compounds. In the same year, Stahly described similar reactions for the synthesis of trifluoromethylated phenols and anilines. Recent Literature. The combination of Et 3 SiH and K 2 S 2 O 8 initiates radical reactions of primary and secondary alkyl bromides or iodides with BPyCu(CF 3) 3 (BPy = 2,2′-bipyridine) in aqueous acetone at room temperature to provide trifluoromethylated products in good yield. The protocol exhibits wide functional group compatibility. H. Shen, Z. Liu, P. Zhang, X. Tan, Z. Zhang, C. Li, J. Journals & Books; Help Download PDF Download. Share. Export. Advanced. Journal of Fluorine Chemistry. Volume , January , Pages Synthesis of trifluoromethyl-substituted bi- and terphenyls by site-selective Suzuki–Miyaura reactions of .